Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Поиск по журналу

Журнал структурной химии

2012 год, номер 5

CONFORMATIONAL ANALYSIS OF 2-ANTHRYLETHYLENE DERIVATIVES: PHOTOCHEMICAL AND COMPUTATIONAL INVESTIGATION

U. Srinivas1, P. Arun kumar1, Srinivas Kolupula2, K. Bhanuprakash3, V. Jayathirtha rao1
1 Organic Division-II, Indian Institute of Chemical Technology
2 Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology National Institute of Pharmaceutical Education and Research (NIPER)
3 Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology
skolupula@niperhyd.ac.in, ksrinivas07@yahoo.com
Ключевые слова: 2-anthryethylene derivatives, photochemical cis-trans isomerization, fluorescence, charge transfer, conformational analysis, theoretical studies
Страницы: 872-886

Аннотация

2-Anthrylethylene derivatives 1E-5E and 1Z are synthesized to study the cis-trans photoisomerization. Interestingly, unlike 9-anthrylethylene derivatives, 2-anthrylethylene derivatives 1E to 5E do not exhibit E (trans) to Z (cis) photoisomerization upon direct and triplet sensitization. One-way Z (cis) to E (trans) photoisomerization of 1Z is found to be very efficient under direct and triplet sensitization conditions, demonstrating the involvement of both singlet and triplet states. 1E-5E exhibits excitation wavelength dependent fluorescence indicating the existence of conformers (rotamers) at room temperature, which is confirmed by fluorescence lifetimes measurements of compounds 1E and 2E. Theoretical studies are carried out at DFT and ab initio methodology and the calculated relative energy difference of the conformers is very small; it ranges between 2.9 kJ·mol-1 to 6.3 kJ·mol-1 for both ground and excited states.