Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

soran2.gif

Baner_Nauka_Sibiri.jpg


Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2014 год, номер 2

YTTRIUM(III) COMPLEX WITH 1,10-PHENANTHROLINE LIGAND: CRYSTAL STRUCTURE AND SPECTROSCOPIC STUDIES

A. Moodi1, M. Khorasani-Motlagh1, M. Noroozifar1, B.O. Patrick2
1University of Sistan & Baluchestan, Zahedan, Iran
mkhorasani@chem.usb.ac.ir
2University of British Columbia, Vancouver, Canada
Ключевые слова: yttrium(III) complex, crystal structure, 1, 10-phenanthroline, X-ray diffraction analysis
Страницы: 358-363
Подраздел: КРИСТАЛЛОХИМИЯ

Аннотация

YCl3×6H2O reacts with 1,10-phenanthroline (phen) to yield a complex of 1:2 yttrium:ligand stoichiometry. The yttrium(III) complex is characterized by the elemental analysis, UV-Vis, IR as well as the X-ray diffraction analysis. The crystal of [Y(phen)2Cl(H2O)3]Cl2×H2O obtained from a methanol solution crystallizes in the triclinic system, space group P2, Z = 2, a = 10.3236(4) Å, b = 10.4566(4) Å, c = 12.5270(5) Å, α = 97.354(2)°, β = 108.740(2)°, γ = 93.458(2)°, Rint = 0.046. The Y(III) ion is eight-coordinated by four nitrogen, three oxygen atoms and one chlorine atom.