Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

soran2.gif

Baner_Nauka_Sibiri.jpg


Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2014 год, номер 4

DICHLOROTRIETHYLPHOSPHINE–[N–FORMYL–N,N'–bis(3,4–DIMETHOXY)BENZYL–TRIMETHYLENEDIAMINE]PLATINUM(II)

O. Şahin1, E.O. Ozcan2, N. Gurbuz2, I. Ozdemir2, O. Buyukgungor3
1Scientific and Technological Research Application and Research Center, Sinop University, Sinop, Turkey
onurs@sinop.edu.tr
2İnönü University, Malatya, Turkey
3Ondokuz Mayıs University, Samsun, Turkey
Ключевые слова: tetrahydropyrimidine, N-formyl-N,N'-bisaryltrimethylenediamine, Pt(II) complex, X-ray diffraction analysis
Страницы: 731-736
Подраздел: КРИСТАЛЛОХИМИЯ

Аннотация

By treatment of 1,3-bis(3,4-dimethoxybenzyl)-3,4,5,6-tetrahydropyrimidinium chloride (1) with KOBu t and [PtCl 2(PEt 3) 2] 2 N -coordinated platinum complex (2) is obtained. The Pt atom is coordinated in square planar arrangements by two chloride ions in a trans-configuration, the N-formyl- N, N'-bisaryltrimethylenediamine nitrogen atom, and the phosphine P atom. An extensive three-dimensional network of three C-H⋯O hydrogen bonds, two C-H⋯π and one π⋯π interactions are responsible for the crystal stabilization. Intermolecular hydrogen bonds and C-H⋯π interactions produce R 2 2(6), R 2 2(22), R 2 2(24), R 3 3(23), R 4 4(26), and R 4 4(32) rings.