Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2014 год, номер 4

FLUORESCENCE AND CRYSTAL STRUCTURES OF NEW MERCURY(II) MACROCYCLIC N-HETEROCYCLIC CARBENE COMPLEXES WITH ETHER CHAINS

J.-W. Wang, M.-C. Zhang
Shanxi Normal University, Linfen, P. R. China
wangjunwen2013@126.com
Ключевые слова: mercury, N-heterocyclic carbene, fluorescence, X-ray structure
Страницы: 737-742
Подраздел: КРИСТАЛЛОХИМИЯ

Аннотация

Polyerther-linked mercury(II) carbene complexes are synthesized by the reaction of carbene precursores with mercury(II) acetate. The binuclear carbene complexes with the chloride ion linkage are easily prepared by the reaction of mononuclear mercury carbene complexes with tetrabutylammoium chloride. The crystal structures reveal that the fluorescence of mercury complexes are related to the coordination mode of the ligands.