CRYSTAL STRUCTURE OF THE COPPER(I) COMPLEX Cu(py–Clan)(PPh3)I
A. D. Khalaji1, K. Jafari2, K. Fejfarova3, M. Dusek3
1Golestan University, Gorgan, Iran ad.khalaji@gu.ac.ir 2Shahrood University of Technology, Shahrood, Iran 3Institute of Physics of the ASCR, Prague, Czech Republic
Ключевые слова: copper(I) complex, Schiff base, synthesis, crystal structure, tetrahedral
Страницы: 183-186 Подраздел: КРАТКИЕ СООБЩЕНИЯ
Аннотация
A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh 3)I], where py-Clan = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh 3)I] complex crystallizes in the monoclinic space group P2 1/ c with unit cell parameters: a = 10.3339(12), b = 34.524, c = 8.3940 Å, β = 114.759(8)°, V = 2719.4(5) Å 3 and Z = 4.
DOI: 10.1134/S0022476615010230 |