Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Поиск по журналу

Журнал структурной химии

2015 год, номер 3

CRYSTAL STRUCTURE OF 2-[BENZYL-(7-OXO-CYCLOHEPTA-1,3,5-TRIENYL)-AMINO]-N-CYCLOHEXYLPROPANAMIDE

A. Ramazani1, S.W. Joo2, I. Amini3, K. Ељlepokura4, T. Lis4, A. Souldozi1
1Islamic Azad University, Zanjan, Iran
aliramazani@gmail.com
2Yeungnam University, Republic of Korea
swjoo@yu.ac.kr
3Payame Noor University, Tehran, Iran
4University of Wrocław, Wrocław, Poland
Ключевые слова: single crystal X-ray structure, smiles rearrangement, Ugi-type coupling, tropolone, cyclohexylisocyanide, benzyl amine, acetaldehyde, Ugi-Smiles-type reaction
Страницы: 498-501
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

The title compound 2-[benzyl-(7-oxo-cyclohepta-1,3,5-trienyl)-amino]-N-cyclohexylpropanemide is synthesized and studied by the single crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H and 13C NMR spectroscopy, and mass spectrometry. The tropone oxygen atom plays an important role in the solid-state molecular structure stabilization by being involved in intramolecular N-H⋯O and C-H⋯O contacts.

DOI: 10.15372/JSC20150310