Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

soran2.gif

Baner_Nauka_Sibiri.jpg


Яндекс.Метрика

Array
(
    [SESS_AUTH] => Array
        (
            [POLICY] => Array
                (
                    [SESSION_TIMEOUT] => 24
                    [SESSION_IP_MASK] => 0.0.0.0
                    [MAX_STORE_NUM] => 10
                    [STORE_IP_MASK] => 0.0.0.0
                    [STORE_TIMEOUT] => 525600
                    [CHECKWORD_TIMEOUT] => 525600
                    [PASSWORD_LENGTH] => 6
                    [PASSWORD_UPPERCASE] => N
                    [PASSWORD_LOWERCASE] => N
                    [PASSWORD_DIGITS] => N
                    [PASSWORD_PUNCTUATION] => N
                    [LOGIN_ATTEMPTS] => 0
                    [PASSWORD_REQUIREMENTS] => Пароль должен быть не менее 6 символов длиной.
                )

        )

    [SESS_IP] => 3.145.66.104
    [SESS_TIME] => 1732193188
    [BX_SESSION_SIGN] => 9b3eeb12a31176bf2731c6c072271eb6
    [fixed_session_id] => 1ad3901ec321c12db410dc0cfbc73a53
    [UNIQUE_KEY] => 2334abf1cde3b405c7d8e42cd0558937
    [BX_LOGIN_NEED_CAPTCHA_LOGIN] => Array
        (
            [LOGIN] => 
            [POLICY_ATTEMPTS] => 0
        )

)

Поиск по журналу

Журнал структурной химии

2015 год, номер 4

CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF A ONE-DIMENSIONAL Cd(II) COORDINATION POLYMER CONSTRUCTED BY 4,4'-DI-TERT-BUTYL-2,2'-BIPYRIDINE AND 5-TERT-BUTYL ISOPHTHALIC ACID

X.J. Xu, J. Wang
Yancheng Teachers University, Yancheng, Jiangsu, P.R. China
wjyctu@gmail.com
Ключевые слова: Cd(II) complex, 4,4'-di-tert-butyl-2,2'-bipyridine, 5-tert-butyl isophthalic acid, crystal structure, luminescence
Страницы: 831-835
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

A one-dimensional Cd(II) complex [Cd(Bu2bpy)(tbip)×H2O]n (1) (Bu2bpy = 4,4'-di-tert-butyl-2,2'-bipyridine, H2tbip = 5-tert-butyl isophthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer based on {Cd2(OCO)2} dimeric kernels with a Cd⋯Cd separation of 4.3197(7) Å. The thermal stability and luminescent properties of the title complex are briefly investigated.

DOI: 10.15372/JSC201504027