CRYSTAL STRUCTURE OF A Ој-OXO-BRIDGED DIMERIC IRON(III) COMPLEX
Y. Yahsi1, E. Gungor1, C. Kazak2, H. Kara1,3
1Balikesir University, Balikesir, Turkey
yahsi@balikesir.edu.tr
2Ondokuz Mayis University, Faculty of Art and Science, Samsun, Turkey
3Mugla Sitki Kocman University, Mugla, Turkey
Ключевые слова: synthesis, Schiff-base ligands, iron (III) complexes, X-ray crystal structure analysis, oxo bridged structure
Страницы: 1601-1605
Аннотация
A dimeric [{Fe(5-ClL1)}2(m-O)], [H2-5-ClL1 = N,N¢-bis(5-Chloro-2-hydroxybenzylidene)- 2-methylpropane-1,2-diamine] tetradentate Schiff-base complex, 1, has been synthesized and its crystal structure has been determined by single crystal X-ray diffraction analysis. Structural analysis of complex 1 shows that the complex is a centrosymmetric dimer. Each of the Fe(III) ions has a five-coordinate geometry and one oxygen atom bridges two Fe(III) ions to form a m-oxo structure. The geometry around iron atom can be described as a square based pyramid with the FeN2O2 coordination plane and oxo ligand.
DOI: 10.15372/JSC20150812 |
