Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

soran2.gif

Baner_Nauka_Sibiri.jpg


Яндекс.Метрика

Array
(
    [SESS_AUTH] => Array
        (
            [POLICY] => Array
                (
                    [SESSION_TIMEOUT] => 24
                    [SESSION_IP_MASK] => 0.0.0.0
                    [MAX_STORE_NUM] => 10
                    [STORE_IP_MASK] => 0.0.0.0
                    [STORE_TIMEOUT] => 525600
                    [CHECKWORD_TIMEOUT] => 525600
                    [PASSWORD_LENGTH] => 6
                    [PASSWORD_UPPERCASE] => N
                    [PASSWORD_LOWERCASE] => N
                    [PASSWORD_DIGITS] => N
                    [PASSWORD_PUNCTUATION] => N
                    [LOGIN_ATTEMPTS] => 0
                    [PASSWORD_REQUIREMENTS] => Пароль должен быть не менее 6 символов длиной.
                )

        )

    [SESS_IP] => 52.91.67.23
    [SESS_TIME] => 1711641857
    [BX_SESSION_SIGN] => 9b3eeb12a31176bf2731c6c072271eb6
    [fixed_session_id] => 9fd44d8a7d31fa56e3df3567a31f0c39
    [UNIQUE_KEY] => 792420b5c1a57a559ad21821869b2768
    [BX_LOGIN_NEED_CAPTCHA_LOGIN] => Array
        (
            [LOGIN] => 
            [POLICY_ATTEMPTS] => 0
        )

)

Поиск по журналу

Журнал структурной химии

2015 год, номер 8

STUDIES ON SPECTROSCOPIC AND CRYSTAL STRUCTURE OF DICHLORO CARBONYL DIPYRIDINE TRIPHENYLARSINE RUTHENIUM(II) COMPLEX

M. Gowri1, T. Srinivasan2, D. Velmurugan2
1Avinashilingam University for Women, Coimbatore - 641 043, Tamilnadu, India
sriadit.gowrisuresh@gmail.com
2University of Madras, Guindy Campus, Chennai - 600 025, Tamilnadu, India
srini771@gmail.com
Ключевые слова: Ru(II) complex, triphenyl arsine, pyridine, chloride, carbonyl complex, crystal structure
Страницы: 1664-1667

Аннотация

The title complex [Ru(Cl)2(CO)(py)2(AsPh3)], was synthesized and characterized. The molecular structure and crystal structures are determined by X-ray crystallography. The dihedral angle between the two cis -pyridine rings is 73.3(2)°, which shows that they are almost orthogonal to each other. The molecular structure is stabilized by inter-molecular and intra-molecular C-H…Cl interactions. The molecular structure is further stabilized by interactions between the aromatic rings.

DOI: 10.15372/JSC20150822